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« on: January 21, 2006, 02:41:46 AM »

What is Ozone?
Ozone is a gas made up of three oxygen atoms (O3). It occurs naturally in small (trace) amounts in the upper atmosphere (the stratosphere). Ozone protects life on Earth from the Sun’s ultraviolet radiation. In the lower atmosphere (the troposphere) near the Earth’s surface, ozone is created by chemical reactions between air pollutants from vehicle exhaust, gasoline vapors, and other emissions. At ground level, high concentrations of ozone are toxic to people and plants.

Stratospheric “good” ozone
Ninety percent of the ozone in the atmosphere sits in the stratosphere, the layer of atmosphere between about 10 and 50 kilometers altitude. The natural level of ozone in the stratosphere is a result of a balance between sunlight that creates ozone and chemical reactions that destroy it. Ozone is created when the kind of oxygen we breathe—O2—is split apart by sunlight into single oxygen atoms. Single oxygen atoms can re-join to make O2, or they can join with O2 molecules to make ozone (O3). Ozone is destroyed when it reacts with molecules containing nitrogen, hydrogen, chlorine, or bromine. Some of the molecules that destroy ozone occur naturally, but people have created others.

The total mass of ozone in the atmosphere is about 3 billion metric tons. That may seem like a lot, but it is only 0.00006 percent of the atmosphere. The peak concentration of ozone occurs at an altitude of roughly 32 kilometers (20 miles) above the surface of the Earth. At that altitude, ozone concentration can be as high as 15 parts per million (0.0015 percent).

The concentration of ozone varies with altitude. Peak concentrations, an average of 8 molecules of ozone per million molecules in the atmosphere, occur between an altitude of 30 and 35 km.
Ozone in the stratosphere absorbs most of the ultraviolet radiation from the Sun. Without ozone, the Sun’s intense UV radiation would sterilize the Earth’s surface. Ozone screens all of the most energetic, UV-c, radiation, and most of the UV-b radiation. Ozone only screens about half of the UV-a radiation. Excessive UV-b and UV-a radiation can cause sunburn and can lead to skin cancer and eye damage.

Solar ultraviolet radiation is largely absorbed by the ozone in the atmosphere—especially the harmful, high-energy UV-a and UV-b. The graph shows the flux (amount of energy flowing through an area) of solar ultraviolet radiation at the top of the atmosphere (top line) and at the Earth’s surface (lower line). The flux is shown on a logarithmic scale, so each tick mark on the y-axis indicates 10-times more energy.
Increased levels of human-produced gases such as CFCs (chlorofluorocarbons) have led to increased rates of ozone destruction, upsetting the natural balance of ozone and leading to reduced stratospheric ozone levels. These reduced ozone levels have increased the amount of harmful ultraviolet radiation reaching the Earth’s surface. When scientists talk about the ozone hole, they are talking about the destruction of stratospheric, “good,” ozone.

Tropospheric “bad” ozone
Although ozone high up in the stratosphere provides a shield to protect life on Earth, direct contact with ozone is harmful to both plants and animals (including humans). Ground-level, “bad,” ozone forms when nitrogen oxide gases from vehicle and industrial emissions react with volatile organic compounds (carbon-containing chemicals that evaporate easily into the air, such as paint thinners). In the troposphere near the Earth’s surface, the natural concentration of ozone is about 10 parts per billion (0.00001 percent). According to the Environmental Protection Agency, exposure to ozone levels of greater than 80 parts per billion for 8 hours or longer is unhealthy. Such concentrations occur in or near cities during periods where the atmosphere is warm and stable. The harmful effects can include throat and lung irritation or aggravation of asthma or emphysema.

Ozone Facts: What is the Ozone Hole?
The ozone hole is not technically a “hole” where no ozone is present, but is actually a region of exceptionally depleted ozone in the stratosphere over the Antarctic that happens at the beginning of Southern Hemisphere spring (August-October). The average concentration of ozone in the atmosphere is about 300 Dobson Units; any area where the concentration drops below 220 Dobson Units is considered part of the ozone hole.

TOTAL OZONE October 4, 2004
The ozone hole is the region over Antarctica with total ozone 220 Dobson Units or lower. This map shows the ozone hole on October 4, 2004. The data were acquired by the Ozone Monitoring Instrument on NASA’s Aura satellite.
Chlorofluorocarbons and ozone
Many people have heard that the ozone hole is caused by chemicals called CFCs, short for chlorofluorocarbons. CFCs escape into the atmosphere from refrigeration and propellant devices and processes, and in the lower atmosphere, they are so stable that they persist for years, even decades. This long lifetime allows some of the CFCs to eventually reach the stratosphere. In the stratosphere, ultraviolet light breaks the bond holding chlorine atoms (Cl) to the CFC molecule. A free chlorine atom goes on to participate in a series of chemical reactions that both destroy ozone and return the free chlorine atom to the atmosphere unchanged, where it can destroy more and more ozone molecules. For those who know the story of CFCs and ozone, that is the part of the tale that is probably familiar.

The part of the story that fewer people know is that while the chlorine atoms freed from CFCs do ultimately destroy ozone, the destruction doesn’t happen immediately. Most of the roaming chlorine that gets separated from CFCs actually becomes part of two chemicals that—under normal atmospheric conditions—are so stable that scientists consider them to be long-term reservoirs for chlorine. So how does the chlorine get out of the reservoir each spring?

Polar stratospheric clouds and ozone
Under normal atmospheric conditions, the two chemicals that store most atmospheric chlorine (hydrochloric acid, and chlorine nitrate) are stable. But in the long months of polar darkness over Antarctica in the winter, atmospheric conditions are unusual. An endlessly circling whirlpool of stratospheric winds called the polar vortex isolates the air in the center. Because it is completely dark, the air in the vortex gets so cold that clouds form, even though the Antarctic air is extremely thin and dry. Chemical reactions take place that could not take place anywhere else in the atmosphere. These unusual reactions can occur only on the surface of polar stratospheric cloud particles, which may be water, ice, or nitric acid, depending on the temperature.

The frozen crytals that make up polar stratospheric clouds provide a surface for the reactions that free chlorine atoms in the Antarctic stratosphere.
These reactions convert the inactive chlorine reservoir chemicals into more active forms, especially gas (Cl2). When the sunlight returns to the South Pole in October, UV light rapidly breaks the bond between the two chlorine atoms, releasing free chlorine into the stratosphere, where it takes part in reactions that destroy ozone molecules while regenerating the chlorine (known as a catalytic reaction). A catalytic reaction allows a single chlorine atom to destroy thousands of ozone molecules. Bromine is involved in a second catalytic reaction with chlorine that contributes a large fraction of ozone loss. The ozone hole grows throughout the early spring until temperatures warm and the polar vortex weakens, ending the isolation of the air in the polar vortex. As air from the surrounding latitudes mixes into the polar region, the ozone-destroying forms of chlorine disperse. The ozone layer stabilizes until the following spring.

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